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Determination of ionization potential of calcium by high-resolution resonance ionization spectroscopy

Miyabe, Masabumi   ; Geppert, C.*; Kato, Masaaki; Oba, Masaki ; Wakaida, Ikuo  ; Watanabe, Kazuo; Wendt, K. D. A.*

High-resolution resonance ionization spectroscopy has been utilized to determine a precise ionization potential of Ca. Three-step resonance excitation with single-mode extended cavity diode lasers populates long and unperturbed Rydberg series of 4snp (1P1) and 4snf (1F3) states in the rage of n=20-150. By using an extended Ritz formula for quantum defect, the series convergence limit has been determined to be 49305.9240 (20) cm$$^{-1}$$ with the accuracy improved one order of magnitude higher than previously reported ones.

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Category:Physics, Multidisciplinary

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