重水中における水和電子・リチウムイオンペアの吸収スペクトルに対する温度効果

Temperature effect on the absorption spectrum of the hydrated electron paired with a lithium cation in deuterated water

Lin, M.; 熊谷 友多   ; 室屋 裕佐*; 勝村 庸介; Lampre, I.*; Coudert, F.*; Boutin, A.*; Mostafavi, M.*

Lin, M.; Kumagai, Yuta; Muroya, Yusa*; Katsumura, Yosuke; Lampre, I.*; Coudert, F.*; Boutin, A.*; Mostafavi, M.*

In this work, we measure the absorption spectra of hydrated electron in DO solutions containing different concentrations of Li+ cations at various temperatures by pulse radiolysis techniques, and perform quantum classical molecular dynamics (QCMD) simulations to explain the shift of the absorption spectra due to the combined effects of temperature and salt concentration.