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Journal Articles

Ion hydration and association in an aqueous calcium chloride solution in the GPa range

Yamaguchi, Toshio*; Nishino, Masaaki*; Yoshida, Koji*; Takumi, Masaharu*; Nagata, Kiyofumi*; Hattori, Takanori

European Journal of Inorganic Chemistry, 2019(8), p.1170 - 1177, 2019/02

 Times Cited Count:16 Percentile:74.07(Chemistry, Inorganic & Nuclear)

Neutron diffraction measurements of an aqueous 2 mol dm$$^{-3}$$ CaCl$$_2$$ solutions in D$$_{2}$$O have been made at 1 GPa, 298 K as well as 0.1 MPa, 298 K. The experimental structure factors are subjected to Empirical Potential Structure Refinement (EPSR) modeling to reveal the ion hydration and association and solvent water at the atomic level. About seven water molecules surround Ca$$^{2+}$$ at the Ca-O and Ca-D distances of 2.44 ${AA}$ and 3.70 ${AA}$, respectively, at both pressures, suggesting no significant pressure effect on the cation hydration. On the other hand, the Cl$$^{-}$$ ion shows a drastic change in water oxygen coordination from 7 at 0.1 MPa to 14 at 1 GPa, accompanied by shortening of Cl-O distance from 3.18 ${AA}$ to 3.15 ${AA}$. However, the number of water hydrogen atoms around Cl$$^{-}$$ does not change significantly as 6.0 $$sim$$ 6.7 with shortening Cl-D distance from 2.22 to 2.18 ${AA}$ on compression. The pressure effect on the solvent water structure is also drastic as an increase in water oxygen atoms of 4.7 at the O-O distance of 2.79 ${AA}$ at 0.1 MPa to 10.3 at 2.85 ${AA}$ at 1 GPa. The number of water hydrogen atoms, however, does not change as 1.2 at the O-D distance of 1.74 ${AA}$ for both pressures, demonstrating the presence of the O$$cdots$$D hydrogen bonds which are significantly bent at 1 GPa at 298 K. This change of hydrogen bonds in water with pressure probably causes the drastic increase in water oxygen atoms around Cl$$^{-}$$.

JAEA Reports

Annual report on the effluent control of low level liquid waste in Nuclear Fuel Cycle Engineering Laboratories FY2014

Watanabe, Hitoshi; Nakano, Masanao; Fujita, Hiroki; Kono, Takahiko; Inoue, Kazumi; Yoshii, Hideki*; Otani, Kazunori*; Hiyama, Yoshinori*; Kikuchi, Masaaki*; Sakauchi, Nobuyuki*; et al.

JAEA-Review 2015-030, 115 Pages, 2015/12

JAEA-Review-2015-030.pdf:25.28MB

Based on the regulations (the safety regulation of Tokai reprocessing plant, the safety regulation of nuclear fuel material usage facilities, the radiation safety rule, the regulation about prevention from radiation hazards due to radioisotopes, which are related with the nuclear regulatory acts, the local agreement concerning with safety and environment conservation around nuclear facilities, the water pollution control law, and bylaw of Ibaraki prefecture), the effluent control of liquid waste discharged from the Nuclear Fuel Cycle Engineering Laboratories of Japan Atomic Energy Agency has been performed. This report describes the effluent control results of the liquid waste in the fiscal year 2014. In this period, the concentrations and the quantities of the radioactivity in liquid waste discharged from the reprocessing plant, the plutonium fuel fabrication facilities, and the other nuclear fuel material usage facilities were much lower than the limits authorized by the above regulations.

Journal Articles

Progress in physics and technology developments for the modification of JT-60

Tamai, Hiroshi; Matsukawa, Makoto; Kurita, Genichi; Hayashi, Nobuhiko; Urata, Kazuhiro*; Miura, Yushi; Kizu, Kaname; Tsuchiya, Katsuhiko; Morioka, Atsuhiko; Kudo, Yusuke; et al.

Plasma Science and Technology, 6(1), p.2141 - 2150, 2004/02

 Times Cited Count:2 Percentile:6.49(Physics, Fluids & Plasmas)

The dominant issue for the the modification program of JT-60 (JT-60SC) is to demonstrate the steady state reactor relevant plasma operation. Physics design on plasma parameters, operation scenarios, and the plasma control method are investigated for the achievement of high-$$beta$$. Engineering design and the R&D on the superconducting magnet coils, radiation shield, and vacuum vessel are performed. Recent progress in such physics and technology developments is presented.

Journal Articles

Objectives and design of the JT-60 superconducting tokamak

Ishida, Shinichi; Abe, Katsunori*; Ando, Akira*; Chujo, T.*; Fujii, Tsuneyuki; Fujita, Takaaki; Goto, Seiichi*; Hanada, Kazuaki*; Hatayama, Akiyoshi*; Hino, Tomoaki*; et al.

Nuclear Fusion, 43(7), p.606 - 613, 2003/07

no abstracts in English

Journal Articles

Objectives and design of the JT-60 superconducting tokamak

Ishida, Shinichi; Abe, Katsunori*; Ando, Akira*; Cho, T.*; Fujii, Tsuneyuki; Fujita, Takaaki; Goto, Seiichi*; Hanada, Kazuaki*; Hatayama, Akiyoshi*; Hino, Tomoaki*; et al.

Nuclear Fusion, 43(7), p.606 - 613, 2003/07

 Times Cited Count:33 Percentile:69.03(Physics, Fluids & Plasmas)

no abstracts in English

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