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Oral presentation

Development of grafted type poly(ether ether ketone) electrolyte membranes; Morphology of PEEK substrate and radiation-induced graft polymerization

Hasegawa, Shin; Chen, J.; Koshikawa, Hiroshi; Iwase, Hiroki; Koizumi, Satoshi; Onuma, Masato*; Maekawa, Yasunari

no journal, , 

Radiation grafting of ethyl styrylsulfonate (EtSS) onto poly(ether ether ketone) (PEEK) film with various crystallinity was performed. The crystallinity in the range of 10$$sim$$30 % has strong influence on the grafting degrees. The PEEK film with crystallinity of 11$$sim$$25 % showed any dose effect on grafting degrees with 60 %. By SAXS analysis, it was found that grafting process strongly depended on lamellar structure into PEEK membrane. The obtained PEEK-based polymer electrolyte membranes with about 12 $$mu$$m thickness showed higher power density than that of Nafion in fuel cell test.

Oral presentation

Observation of carboxymethyl cellulose radicals in aqueous solution by ESR method

Saiki, Seiichi; Nagasawa, Naotsugu; Hiroki, Akihiro; Morishita, Norio; Taguchi, Mitsumasa; Seko, Noriaki; Kudo, Hisaaki*; Katsumura, Yosuke*

no journal, , 

no abstracts in English

Oral presentation

Synthesis on pilot scale of anion adsorbent that uses biodegradability material

Kasai, Noboru; Hoshina, Hiroyuki; Seko, Noriaki; Shibata, Takuya*; Takahashi, Makikatsu*

no journal, , 

no abstracts in English

Oral presentation

Preparation of blend hydrogels based on hydroxypropyl cellulose and poly(vinyl alcohol)

Hiroki, Akihiro; Sato, Toshihiro*; Nagasawa, Naotsugu; Taguchi, Mitsumasa; Tamada, Masao

no journal, , 

no abstracts in English

Oral presentation

Oxygen reduction activity of N-doped carbon based films prepared by pulsed laser deposition

Hakoda, Teruyuki; Yamamoto, Shunya; Kawaguchi, Kazuhiro; Yamaki, Tetsuya; Kobayashi, Tomohiro*; Yoshikawa, Masahito

no journal, , 

no abstracts in English

Oral presentation

Synthesis of catalytic metal-chelating polycarbosilane polymer prepared by radiation grafting

Yoshimura, Kimio; Hakoda, Teruyuki; Sugimoto, Masaki; Yamamoto, Shunya; Yoshikawa, Masahito

no journal, , 

no abstracts in English

Oral presentation

Preparation of porous fluoropolymer membranes by ion beam irradiation; Size and shape control of "Track-Etched Pores"

Yamaki, Tetsuya; Nuryanthi, N.; Koshikawa, Hiroshi; Sawada, Shinichi; Hasegawa, Shin; Asano, Masaharu; Maekawa, Yasunari; Voss, K.-O.*; Trautmann, C.*; Neumann, R.*

no journal, , 

Poly(vinylidene fluoride) (PVDF) membranes with conical and cylindrical nanopores were prepared in a controlled manner by the ion-track technique, which involved heavy ion beam irradiation and subsequent alkaline etching. The etching behavior mainly depended on the energy deposition of the ion beams, and thus its depth distribution, estimated by theoretical simulation, was successfully applied to control the shapes and diameters of the etched pores. Scanning electron microscopy (SEM) and electrolytic conductometry provided an insight into the critical experimental parameters.

Oral presentation

Enhanced reactivity and polymerization kinetics of ion-track grafting

Sekine, Toshihiko; Sawada, Shinichi; Yamaki, Tetsuya; Koshikawa, Hiroshi; Asano, Masaharu; Suzuki, Akihiro*; Terai, Takayuki*; Maekawa, Yasunari

no journal, , 

no abstracts in English

Oral presentation

Microhole structures of radiation-grafted polymer electrolyte membranes investigated by positron annihilation lifetime spectroscopy

Sawada, Shinichi; Yabuuchi, Atsushi; Maekawa, Masaki; Kawasuso, Atsuo; Maekawa, Yasunari

no journal, , 

no abstracts in English

Oral presentation

Radiolysis of extractants for separation of actinides by irradiation with helium ion beam

Sugo, Yumi; Taguchi, Mitsumasa; Sasaki, Yuji; Morita, Yasuji

no journal, , 

no abstracts in English

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