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Yoshida, Koji*; Sanada, Yusuke*; Yamaguchi, Toshio*; Matsuura, Masato*; Tamatsukuri, Hiromu; Uchiyama, Hiroshi*
Journal of Molecular Liquids, 366, p.120218_1 - 120218_9, 2022/11
Times Cited Count:1 Percentile:13.89(Chemistry, Physical)Yokoi, Naoto*; Saito, Eiji
Journal of Magnetism and Magnetic Materials, 545, p.168673_1 - 168673_12, 2022/03
Times Cited Count:0 Percentile:0(Materials Science, Multidisciplinary)Yano, Yoshio*; Ono, Toshikazu*; Ohara, Takashi; Hisaeda, Yoshio*
Chemistry; A European Journal, 27(71), p.17802 - 17807, 2021/12
Times Cited Count:4 Percentile:35.86(Chemistry, Multidisciplinary)Kawakita, Yukinobu; Kikuchi, Tatsuya*; Tahara, Shuta*; Nakamura, Mitsutaka; Inamura, Yasuhiro; Maruyama, Kenji*; Yamauchi, Yasuhiro*; Kawamura, Seiko; Nakajima, Kenji
JPS Conference Proceedings (Internet), 33, p.011071_1 - 011071_6, 2021/03
CuI is a well-known superionic conductor in a high temperature solid phase where the mobile cations migrate between interstitial sites in the f.c.c. sublattice formed by iodine ions. Even in the molten state, it shows several features suggesting collective or cooperative ionic motion. MD results show that Cu diffuses much faster than I. The Cu-Cu partial structure factor have a FSDP which indicates a medium-range ordering of Cu ions. Moreover the Cu-Cu partial pair distribution deeply penetrates into the nearest neighboring Cu-I shell. To reveal origin such anomalous behaviors of molten CuI, we performed quaiselastic neutron scattering (QENS) by the disk-chopper spectrometer AMATERAS at MLF, J-PARC. To interpret the total dynamic structure factor obtained from coherent QENS, the mode distribution analysis was applied. It is found that the motion of iodine is a kind of fluctuating within an almost local area while Cu ions diffuse much faster than iodine ions.
Luo, P.*; Zhai, Y.*; Leao, J. B.*; Kofu, Maiko; Nakajima, Kenji; Faraone, A.*; Zhang, Y.*
Journal of Physical Chemistry Letters (Internet), 12(1), p.392 - 398, 2021/01
Times Cited Count:4 Percentile:33.96(Chemistry, Physical)Using neutron spin-echo spectroscopy, we studied the microscopic structural relaxation of a prototypical network ionic liquid ZnCl at the structure factor primary peak and prepeak. The results show that the relaxation at the primary peak is faster than the prepeak and that the activation energy is % higher. A stretched exponential relaxation is observed even at temperatures well-above the melting point . Surprisingly, the stretching exponent shows a rapid increase upon cooling, especially at the primary peak, where it changes from a stretched exponential to a simple exponential on approaching the . These results suggest that the appearance of glassy dynamics typical of the supercooled state even in the equilibrium liquid state of ZnCl as well as the difference of activation energy at the two investigated length scales are related to the formation of a network structure on cooling.
Kofu, Maiko; Yamamuro, Osamu*
Journal of the Physical Society of Japan, 89(5), p.051002_1 - 051002_12, 2020/05
Times Cited Count:3 Percentile:30.12(Physics, Multidisciplinary)The behavior of hydrogen in metals has attracted much attention in fundamental and applied research areas for many decades. Among metals, palladium is remarkable in that it can absorb large quantities of hydrogen, and hydrogen atoms are highly mobile in the fcc Pd lattice. The dynamics of hydrogen in Pd have been investigated by means of neutron spectroscopy which is the best tool to provide insights into microscopic dynamics of hydrogen atoms. In this article, we review recent and historical neutron scattering works to facilitate the latest understanding of the hydrogen dynamics in bulk and nanometer-sized Pd hydrides.
Ideta, Shinichiro*; Murai, Naoki; Nakajima, Masamichi*; Kajimoto, Ryoichi; Tanaka, Kiyohisa*
Physical Review B, 100(23), p.235135_1 - 235135_7, 2019/12
Times Cited Count:3 Percentile:15.75(Materials Science, Multidisciplinary)Yokoi, Naoto*; Sato, Koji*; Saito, Eiji
Physical Review D, 100(10), p.106012_1 - 106012_9, 2019/11
Times Cited Count:2 Percentile:13.54(Astronomy & Astrophysics)Sumida, Kazuki*; Kakoki, Masaaki*; Reimann, J.*; Nurmamat, M.*; Goto, Shinichi*; Takeda, Yukiharu; Saito, Yuji; Kokh, K. A.*; Tereshchenko, O. E.*; Gdde, J.*; et al.
New Journal of Physics (Internet), 21(9), p.093006_1 - 093006_8, 2019/09
Times Cited Count:11 Percentile:64.02(Physics, Multidisciplinary)Tang, J.*; Yamamoto, Susumu*; Koitaya, Takanori*; Yoshigoe, Akitaka; Tokunaga, Takuma*; Mukai, Kozo*; Matsuda, Iwao*; Yoshinobu, Jun*
Applied Surface Science, 480, p.419 - 426, 2019/06
Times Cited Count:10 Percentile:48.61(Chemistry, Physical)Mass transports during hydrogen adsorption and absorption processes of PdCu alloys that has advantages of higher hydrogen diffusivity and economically lower-cost than the other Pd-alloys were studied. The research was made with a comparison of the well-known ordered phase of the bcc structure (the B2 phase) and a mixed phase of the fcc and B2 structures. ultrahigh vacuum X-ray photoelectron spectroscopy and ambient pressure X-ray photoelectron spectroscopy using synchrotron radiation were carried out to trace the chemical states of the Pd and Cu atoms as a function of temperatures. It is elucidated that the initial adsorption and absorption processes were similar in the two phases, but a hydrogen diffusion rate to the bulk was higher in the ordered phase than in the mixed one. We found the dynamics of the Pd and Cu atoms during the hydrogen adsorption/absorption processes largely depend on temperature. In the hydrogen atmosphere, the Pd atoms segregate at the surface below 373 K and Cu atoms segregate at the surface above 373 K. The present results agree well with the previous theoretical calculations and, thus, provide appropriate inputs toward developments of the hydrogen permeation materials.
Kawakita, Yukinobu; Kikuchi, Tatsuya*; Inamura, Yasuhiro; Tahara, Shuta*; Maruyama, Kenji*; Hanashima, Takayasu*; Nakamura, Mitsutaka; Kiyanagi, Ryoji; Yamauchi, Yasuhiro*; Chiba, Kaori*; et al.
Physica B; Condensed Matter, 551, p.291 - 296, 2018/12
Times Cited Count:11 Percentile:47.29(Physics, Condensed Matter)There are elemental liquid metals with complex structures far from the hard sphere (HS) packing model. Liquid Bi has an asymmetric first peak in the structure factors S(Q). The pair distribution function g(r) exhibits strange distance ratio of 1:2 between the first and the second peaks. Since a HS model with two kinds of radius produces asymmetry of the main peak in S(Q), existence of short-lived covalent bonds was discussed. Contrarily, modulation of the atomic distribution by the Friedel oscillations of shielding electrons around metallic ions was discussed. To examine its bonding nature from viewpoints of dynamic correlation functions, we have measured neutron quasielastic scattering of liquid Bi by using cold disk chopper spectrometer installed at MLF of J-PARC. The van Hove function revealed that the shoulder structure located at a longer side of the first peak in g(r) exhibits a longer relaxation time than the main structures such as the first and second peaks.
Murai, Naoki; Suzuki, Katsuhiro*; Ideta, Shinichiro*; Nakajima, Masamichi*; Tanaka, Kiyohisa*; Ikeda, Hiroaki*; Kajimoto, Ryoichi
Physical Review B, 97(24), p.241112_1 - 241112_6, 2018/06
Times Cited Count:5 Percentile:25.26(Materials Science, Multidisciplinary)We use inelastic neutron scattering (INS) to investigate the effect of electron correlations on spin dynamics in iron-based superconductor BaKFeAs. Our INS data show a spin-wave-like dispersive feature, with a zone boundary energy of 200 meV. A first principles analysis of dynamical spin susceptibility, incorporating the mass renormalization factor of 3, as determined by angle-resolved photoemission spectroscopy, provides a reasonable description of the observed spin excitations. This analysis shows that electron correlations in the Fe-3d bands yield enhanced effective electron masses, and consequently, induce substantial narrowing of the spin excitation bandwidth. Our results highlight the importance of electron correlations in an itinerant description of the spin excitations in iron-based superconductors.
Matsuo, Tatsuhito; Arata, Toshiaki*; Oda, Toshiro*; Nakajima, Kenji; Kawamura, Seiko; Kikuchi, Tatsuya; Fujiwara, Satoru
Biochemistry and Biophysics Reports (Internet), 6, p.220 - 225, 2016/07
Itakura, Ryuji
Reza Kenkyu, 43(3), p.136 - 137, 2015/03
Recently, technique of pulsed electron beam generation combined with ultrafast laser technology has been developed for realization of time-resolved measurements. A variety of methods such as an electron gun with a photo-cathode and an optical gating of a CW electron beam are proposed and demonstrated. We will compiles topical papers on frontier of pulsed electron beam for research on photoexcited dynamics in one volume of "The Review of Laser Engineering". This paper is a preface for describing the aim and contents of this special volume.
Yoshigoe, Akitaka; Teraoka, Yuden; Okada, Ryuta; Yamada, Yoichi*; Sasaki, Masahiro*
Journal of Chemical Physics, 141(17), p.174708_1 - 174708_7, 2014/11
Times Cited Count:8 Percentile:29.47(Chemistry, Physical)synchrotron radiation photoelectron spectroscopy was performed during the oxidation of the Ge(100)-21 surface induced by a molecular oxygen beam with various incident energies up to 2.2 eV from the initial to saturation coverage of surface oxides. The saturation coverage of oxygen on the clean Ge(100) surface was much lower than one monolayer and the oxidation state of Ge was +2 at most. This indicates that the Ge(100) surface is in strong contrast to Si surfaces. The direct adsorption process can be activated by increasing the translational energy, resulting in an increased population of Ge and a higher final oxygen coverage. Our findings will contribute to the fundamental understanding of oxygen adsorption processes at 300 K from the initial stages to saturated oxidation.
Machida, Masahiko; Koyama, Tomio*; Kato, Masaru*; Ishida, Takekazu*
Physica C, 426-431(1), p.169 - 173, 2005/10
no abstracts in English
Takayanagi, Toshiyuki
Chemical Physics, 308(3), p.211 - 216, 2005/01
Times Cited Count:6 Percentile:20.33(Chemistry, Physical)no abstracts in English
Takase, Kazuyuki; Yoshida, Hiroyuki; Ose, Yasuo*
Hai Pafomansu Komputingu To Keisan Kagaku Shimpojium (HPCS 2005) Rombunshu, P. 16, 2005/01
no abstracts in English
Takayanagi, Toshiyuki
Chemical Physics, 302(1-3), p.85 - 93, 2004/07
Times Cited Count:12 Percentile:36.75(Chemistry, Physical)no abstracts in English
Takayanagi, Toshiyuki; Shiga, Motoyuki
Physical Chemistry Chemical Physics, 6(13), p.3241 - 3247, 2004/07
Times Cited Count:29 Percentile:67.72(Chemistry, Physical)no abstracts in English