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Kato, Tomoaki; Yamagishi, Isao
JAEA-Technology 2023-018, 53 Pages, 2023/11
JAEA-Technology-2023-018.pdf:2.6MB
In the decommissioning of Fukushima Daiichi Nuclear Power Station, radioactive carbonate slurry waste was generated using the Advanced Liquid Processing System (ALPS) pretreatment and temporarily stored in a high integrity container (HIC). In 2015, overflow of supernatant from HIC estimate as bubble retention in the carbonate slurry was discovered, increasing the need for a safety assessment of the carbonate slurry stored the HIC (HIC slurry). In this study, a carbonate slurry (simulated slurry) was prepared according to the Mg/Ca mass ratio in the ALPS inlet water of the HIC slurry which overflew the HIC. The effects of reaction time during the pretreatment process, suspended solids concentration (SS concentration), and settling time on the particle composition, morphology and rheological properties of the slurry were investigated. Evaluating the effect of reaction time and concentration process on chemical properties in slurry production, the effect of the reaction time was not confirmed in the simulated slurry that had undergone the concentration process, and slurry prepared at SS concentration of 150 g/L was composed of formless particles have a particle diameter of 0.4 
m or less. We also investigate the effect of SS concentration on sedimentability, decrease in SS concentration by dilution with processing solution contributed to an increase in the initial slurry settling velocity. Furthermore, two different flow characteristics were observed depending on the settling time, suggesting that the slurry at the initial settling time has non-Bingham flow properties, whereas it changes to Bingham flow properties as the settling time becomes longer. In addition, yield stress was increased with settling time, and this yield stress was found to be exponentially proportional to the density of the slurry. These results provide knowledge to estimate the current state of HIC slurry and are expected to contribute to the safety assessment.
Sasaki, Yuji; Kaneko, Masashi; Ban, Yasutoshi; Kinoshita, Ryoma; Matsumiya, Masahiko*; Shinoku, Kota*; Shiroishi, Hidenobu*
Analytical Sciences, 39(9), p.1575 - 1583, 2023/09
Times Cited Count：0 Percentile：0(Chemistry, Analytical)Extraction of Rh from HCl can be performed by NTAamide(C6) (hexahexyl-nitrilotriacetamide) and other related compounds into n-dodecane. We use ion-pair extraction of anionic species of Rh-chloride and protonated extractant. Rh behave as anion in hydrochloric acid and the tertiary nitrogen atom in extractant may be protonated to produce the quaternary amine in acidic condition. From the present work, the maximum distribution ratio of Rh(III) is 16. The D(Rh) values are changeable during preparation of the aqueous solutions because different Rh-Cl-H
O complexes are formed in HCl media and show the slow exchange rate between Cl and HO. Using the UV spectrum, Rh-chloride solution having the peak of spectrum at 504 nm can be extracted effectively, where RhCl
(HO)
and RhCl
(H
O)
exist mainly from DFT calculation. Stoichiometry of one-one complex of Rh and NTAamide is obtained from slope analysis, and 85 mM of concentrated Rh ion can be extracted.
RhSiShamoto, Shinichi; Yamauchi, Hiroki; Iida, Kazuki*; Ikeuchi, Kazuhiko*; Hall, A. E.*; Chen, Y.-S.*; Lee, M. K.*; Balakrishnan, G.*; Chang, L.-J.*
Communications Physics (Internet), 6, p.248_1 - 248_6, 2023/09
Times Cited Count：1 Percentile：52.21(Physics, Multidisciplinary)We show that the local spin correlation order has a spiral structure by neutron scattering measurement of a MnRhSi single crystal. The possible origins of the magnetic cluster formation are discussed in terms of the Lifshitz invariant and the Griffiths phase, and compared with the room-temperature skyrmion phase of Co
ZnMn
and non-Fermi liquid behavior of 
-Mn.
Zn
Kitazawa, Takafumi; Ikeda, Yoichi*; Sakakibara, Toshiro*; Matsuo, Akira*; Shimizu, Yusei*; Tokunaga, Yo; Haga, Yoshinori; Kindo, Koichi*; Nambu, Yusuke*; Ikeuchi, Kazuhiko*; et al.
Physical Review B, 108(8), p.085105_1 - 085105_7, 2023/08
Yakushev, A.*; Lens, L.*; D
llmann, Ch. E.*; Khuyagbaatar, J.*; J
ger, E.*; Krier, J.*; Runke, J.*; Albers, H. M.*; Asai, Masato; Block, M.*; et al.
Frontiers in Chemistry (Internet), 10, p.976635_1 - 976635_11, 2022/08
Times Cited Count：11 Percentile：81.01(Chemistry, Multidisciplinary)Flerovium (Fl, element 114) is the heaviest element chemically studied so far. The first chemical experiment on Fl suggested that Fl is a noble-gas-like element, while the second studies suggested that Fl has a volatile-metal-like character. To obtain more reliable conclusion, we performed further experimental studies on Fl adsorption behavior on Si oxide and gold surfaces. The present results suggest that Fl is highly volatile and less reactive than the volatile metal, Hg, but has higher reactivity than the noble gas, Rn.
Kataoka, Takahiro*; Naoe, Shota*; Murakami, Kaito*; Yukimine, Ryohei*; Fujimoto, Yuki*; Kanzaki, Norie; Sakoda, Akihiro; Mitsunobu, Fumihiro*; Yamaoka, Kiyonori*
Journal of Clinical Biochemistry and Nutrition, 70(2), p.154 - 159, 2022/03
Times Cited Count：3 Percentile：41.28(Nutrition & Dietetics)Khuyagbaatar, J.*; Yakushev, A.*; Dllmann, Ch. E.*; Ackermann, D.*; Andersson, L.-L.*; Asai, Masato; Block, M.*; Boll, R. A.*; Brand, H.*; Cox, D. M.*; et al.
Physical Review C, 102(6), p.064602_1 - 064602_9, 2020/12
Times Cited Count：45 Percentile：98.21(Physics, Nuclear)A search for production of the superheavy elements with atomic numbers 119 and 120 was performed in the 
Ti+
Bk and Ti+Cf fusion-evaporation reactions, respectively, at the gas-filled recoil separator TASCA. Over four months of irradiation, neither was detected at cross-section sensitivity levels of 65 and 200 fb, respectively. The non-observation of elements 119 and 120 is discussed within the concept of fusion-evaporation reactions including various theoretical predictions on the fission-barrier heights of superheavy nuclei in the region of the island of stability.
Shimizu, Yusei*; Miyake, Atsushi*; Maurya, A.*; Honda, Fuminori*; Nakamura, Ai*; Sato, Yoshiki*; Li, D.*; Homma, Yoshiya*; Yokoyama, Makoto*; Tokunaga, Yo; et al.
Physical Review B, 102(13), p.134411_1 - 134411_11, 2020/10
Times Cited Count：6 Percentile：37.51(Materials Science, Multidisciplinary)Aritomo, Yoshihiro*; Amano, Shota*; Okubayashi, Mizuki*; Yanagi, Baku*; Nishio, Katsuhisa; Ota, Masahisa*
Physics of Atomic Nuclei, 83(4), p.545 - 549, 2020/07
Times Cited Count：0 Percentile：0.02(Physics, Nuclear)Uchibori, Akihiro; Yanagisawa, Hideki*; Takata, Takashi; Li, J.*; Jang, S.*
Mechanical Engineering Journal (Internet), 7(3), p.19-00548_1 - 19-00548_11, 2020/06
Evaluation of occurrence possibility of tube failure propagation under sodium-water reaction accident is an important issue. In this study, a numerical analysis method to predict occurrence of failure propagation by overheating rupture was constructed to expand application range of an existing computer code. Applicability of the method was constructed through the numerical analysis of the experiment on water vapor discharging in liquid sodium. To improve the evaluation accuracy for the temperature distribution, a Lagrangian particle model for simulating reacting jet was also developed as an alternative method and its basic function was confirmed.
dispersive X-ray absorption fine structure spectroscopySong, C.*; Seo, O.*; Matsumura, Daiju; Hiroi, Satoshi*; Cui, Y.-T.*; Kim, J.*; Chen, Y.*; Tayal, A.*; Kusada, Kohei*; Kobayashi, Hirokazu*; et al.
RSC Advances (Internet), 10(34), p.19751 - 19758, 2020/05
Times Cited Count：0 Percentile：0(Chemistry, Multidisciplinary)Lessux, G. G.*; Sakai, Hironori; Hattori, Taisuke*; Tokunaga, Yo; Kambe, Shinsaku; Kuhns, P. L.*; Reyes, A. P.*; Thompson, J. D.*; Pagliuso, P. G.*; Urbano, R. R.*
Physical Review B, 101(16), p.165111_1 - 165111_6, 2020/04
Times Cited Count：7 Percentile：42.63(Materials Science, Multidisciplinary)CeRhIn is a Kondo-lattice prototype in which a magnetic field 
31T induces an abrupt Fermi-surface (FS) reconstruction and pronounced in-plane electrical transport anisotropy all within its antiferromagnetic state. Here we report low-temperature nuclear magnetic resonance (NMR) measurements revealing a pronounced decrease in the 
In formal Knight shift, without changes in crystal or magnetic structures, of CeRhIn at fields (
) spanning . We discuss the emergent state above in terms of a change in Ce's 4
orbitals that arises from field-induced evolution of crystal-electric field (CEF) energy levels. This change in orbital character enhances hybridization between the 4 and the conduction electrons that leads ultimately to an itinerant quantum-critical point at 
50T.
Suzuki, Tomoya*; Ogata, Takeshi*; Tanaka, Mikiya*; Kobayashi, Toru; Shiwaku, Hideaki; Yaita, Tsuyoshi; Narita, Hirokazu*
Analytical Sciences, 35(12), p.1353 - 1360, 2019/12
Times Cited Count：4 Percentile：16.62(Chemistry, Analytical)no abstracts in English
-HF mixture; Kinetics and mechanismSimonnet, M.; Barr
, N.*; Drot, R.*; Le Naour, C.*; Sladkov, V.*; Delpech, S.*
Radiochimica Acta, 107(4), p.289 - 297, 2019/04
Times Cited Count：3 Percentile：30.79(Chemistry, Inorganic & Nuclear)Iwase, Hiroki*; Kawai, Risa*; Morishima, Ken*; Takata, Shinichi; Yoshimura, Tomokazu*; Shibayama, Mitsuhiro*
Journal of Colloid and Interface Science, 538, p.357 - 366, 2019/03
Times Cited Count：13 Percentile：41.04(Chemistry, Physical) and Au surfaces in preparation for chemical investigations on Cn, Nh, and Fl at TASCALens, L.*; Yakushev, A.*; Dllmann, Ch. E.*; Asai, Masato; Ballof, J.*; Block, M.*; David, H. M.*; Despotopulos, J.*; Di Nitto, A.*; Eberhardt, K.*; et al.
Radiochimica Acta, 106(12), p.949 - 962, 2018/12
Times Cited Count：8 Percentile：61.87(Chemistry, Inorganic & Nuclear)Online gas-solid adsorption studies with single atom quantities of Hg, Tl, and Pb on SiO and Au surfaces were carried out using short-lived radioisotopes with half-lives in the range of 4-49 s. This is a model study to measure adsorption enthalpies of superheavy elements Cn, Nh, and Fl. The short-lived isotopes were produced and separated by the gas-filled recoil separator TASCA at GSI. The products were stopped in He gas, and flushed into gas chromatography columns made of Si detectors whose surfaces were covered by SiO or Au. The short-lived Tl and Pb were successfully measured by the Si detectors with the SiO surface at room temperature. On the other hand, the Hg did not adsorb on the SiO surface, but adsorbed on the Au surface. The results demonstrated that the adsorption properties of short-lived Hg, Tl, and Pb could be studied with this setup, and that this method is applicable to the experiment for Cn, Nh, and Fl.
Uchibori, Akihiro; Yanagisawa, Hideki*; Takata, Takashi; Ohshima, Hiroyuki
Proceedings of 11th Korea-Japan Symposium on Nuclear Thermal Hydraulics and Safety (NTHAS-11) (Internet), 6 Pages, 2018/11
Evaluation of occurrence possibility of tube failure propagation under sodium-water reaction accident is an important issue. In this study, a numerical analysis method to predict occurrence of failure propagation by overheating rupture was constructed to expand application range of an existing computer code. Applicability of the method was constructed through the numerical analysis of the experiment on water vapor discharging in liquid sodium.
Uchibori, Akihiro; Takata, Takashi; Yanagisawa, Hideki*; Li, J.*; Jang, S.*
Proceedings of 2018 ANS Winter Meeting and Nuclear Technology Expo; Embedded Topical International Topical Meeting on Advances in Thermal Hydraulics (ATH 2018) (USB Flash Drive), p.1289 - 1294, 2018/11
Evaluation of occurrence possibility of tube failure propagation under sodium-water reaction accident is an important issue. In this study, a numerical analysis method to predict occurrence of failure propagation by overheating rupture was constructed to expand application range of an existing computer code. Applicability of the method was constructed through the numerical analysis of the experiment on water vapor discharging in liquid sodium. To improve the evaluation accuracy for the temperature distribution, a Lagrangian particle model for simulating reacting jet was also developed as an alternative method and its basic function was confirmed.
Maekawa, Fujio; Sasa, Toshinobu
Enerugi Rebyu, 37(9), p.15 - 18, 2017/08
Accelerator driven nuclear transmutation systems (ADS) are under development for reducing nuclear waste. The J-PARC Transmutation Experimental Facility program and situation of the world for the ADS development are introduced.
Hashiba, Kimihiro*; Fukui, Katsunori*; Sugita, Yutaka; Aoyagi, Kazuhei
Proceedings of ITA-AITES World Tunnel Congress 2017 (WTC 2017) (USB Flash Drive), 8 Pages, 2017/06
It is essential to understand the mechanical and rheological characteristics of diatomaceous and siliceous mudstones for the construction of underground structures and for the assessment of their long-term stability. In this study, the siliceous mudstone of the Wakkanai Formation was applied to various laboratory tests: compression test, creep test, relaxation test, drying shrinkage test, and slaking test. The test results showed that water has a major impact on the mechanical and rheological properties of the siliceous mudstone. In addition, water content at a tunnel wall was measured in the Horonobe URL. Comparing the results of the laboratory tests and the in situ measurement, the effect of water on the tunnel stability was discussed.
