XAFS study of molten ZrCl in LiCl-KCl eutectic

Okamoto, Yoshihiro ; Motohashi, Haruhiko*

The local structure of molten ZrCl in LiCl-KCl eutectic was investigated by using an X-ray absorption fine structure(XAFS) of the Zr K-absorption edge. The nearest Zr $^{4+}$ -Cl distance and coordination number from the curve fitting analysis were 2.51 and 5.80.6, respectively. These suggest that a 6-fold coordination (ZrCl) $^{2-}$ is predominant in the mixture melt.

Language	:	English
Journal	:	Zeitschrift fr Naturforschung, A
Volume	:	579
Number	:	5
Pages	:	p.277 - 280
Publication Year/Month	:	2002/05
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Keywords	:	Molten Salt; XAFS; Zirconium Chloride; Local Structure; High Temperature; Synchrotron Radiation
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Registration No. : A20020133
JAEA Abstracts No. : 301252
Paper Submission No. : 19666

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