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X-ray structural analysis of molten PbCl$$_2$$

Okamoto, Yoshihiro ; Iwadate, Yasuhiko*; Fukushima, Kazuko*; Matsuura, Haruaki*; Minato, Kazuo 

The structure of molten PbCl$$_2$$ was investigated by using X-ray diffrtaction(XRD) and X-ray absorption fine structure(XAFS) analysis techniques. From the fourier transformation analysis if the XRD data, the nearest Pb$$^{2+}$$-Cl$$^-$$ interaction consists of two kinds of interactions; rigid 4-fold tetrahedron and 2-3 loose coordination. The XAFS result shows a local structure is the 4-fold coordination in the melt.

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Category:Chemistry, Multidisciplinary

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