Photoluminescence and Raman studies of curium and americium complexes of 6-methyl 2-(2-pyridyl)- benzimidazole; Evidence for an efficient intramolecular energy transfer

Assefa, Z.*; Yaita, Tsuyoshi; Haire, R. G.*; Tachimori, Shoichi

The 6-methyl- 2-(2-pyridyl)-benzimidazole (biz) ligand coordinates with the actinide species in solution, and the complexes display efficient intra-molecular energy-transfer processes. The energy transfer in the Cm(III):biz system proceeds in a non-radiative mode, whereas a radiative mode is the principal mechanism in the Am(III)-biz system.

Language	:	English
Journal	:	Inorganic Chemistry
Volume	:	42
Number	:	23
Pages	:	p.7375 - 7377
Publication Year/Month	:	2003/11
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Paper URL	:	https://doi.org/10.1021/ic034759y
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Keywords	:	Photoluminescence; Raman; Cm; Am; Benzimidazole; Energy Transfer; Complex; Solution
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InCites™	:	Percentile:36.73 Category:Chemistry, Inorganic & Nuclear
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Registration No. : A20030438
JAEA Abstracts No. : 320099
Paper Submission No. : 20633

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