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Photoluminescence and Raman studies of curium and americium complexes of 6-methyl 2-(2-pyridyl)- benzimidazole; Evidence for an efficient intramolecular energy transfer

Assefa, Z.*; Yaita, Tsuyoshi; Haire, R. G.*; Tachimori, Shoichi

The 6-methyl- 2-(2-pyridyl)-benzimidazole (biz) ligand coordinates with the actinide species in solution, and the complexes display efficient intra-molecular energy-transfer processes. The energy transfer in the Cm(III):biz system proceeds in a non-radiative mode, whereas a radiative mode is the principal mechanism in the Am(III)-biz system.

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Category:Chemistry, Inorganic & Nuclear

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