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Selective separation of Am(III) from lanthanides(III) by solvent extraction with hydrophobic field of "superweak" anion

Naganawa, Hirochika ; Suzuki, Hideya*; Noro, Junji*; Kimura, Takaumi 

A "superweak" anion, TFPB-, gives rise to a field effect on the selectivity for Am$$^{3+}$$ over Ln$$^{3+}$$ in their extraction from aqueous HNO$$_{3}$$ solution into benzene containing a "hard donor" extractant that shows no selectivity for these metal ions in traditional solvent extraction.

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