Selective OD bond dissociation of HOD; Photodissociation of vibrationally excited HOD in the 5 $_{OD}$ state

Akagi, Hiroshi; Fukazawa, Hiroshi; Yokoyama, Keiichi ; Yokoyama, Atsushi

Vibrationally excited HOD in the fourth overtone state of the OD-stretching mode (5 $_{OD}$ ) has been photodissociated by ultraviolet photolysis at ca. 243.1 nm. Branching ratio between the OH- and OD-bond dissociation channels has been determined by detecting the H and D atoms. The OD-bond dissociation is the dominant channel, with the yield of H atom generated by the photolysis being below the detection limit.

Language	:	English
Journal	:	Journal of Chemical Physics
Volume	:	123
Number	:	18
Pages	:	p.184305_1 - 184305_7
Publication Year/Month	:	2005/11
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Paper URL	:	https://doi.org/10.1063/1.2104532
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Keywords	:	紫外光分解; 水; 重水素; 選択的結合切断; 振動励起
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Registration No. : A20050246
JAEA Abstracts No. : 34000085
Paper Submission No. : 234

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Selective OD bond dissociation of HOD; Photodissociation of vibrationally excited HOD in the 5 state

Selective OD bond dissociation of HOD; Photodissociation of vibrationally excited HOD in the 5 $_{OD}$ state