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Polymeric Co-C$$_{60}$$ compound phase evolved in atomistically mixed thin films

Sakai, Seiji; Naramoto, Hiroshi*; Lavrentiev, V.*; Narumi, Kazumasa; Maekawa, Masaki; Kawasuso, Atsuo; Yaita, Tsuyoshi; Baba, Yuji  

A systematic study of the atom-level mixtures between Co and C$$_{60}$$ has made possible to find a new C$$_{60}$$-based compound phase, Co$$_{x}$$C$$_{60}$$ (x$$leq$$5). It is confirmed with the EXAFS analysis and the positron annihilation study that the polymeric structure is developed three-dimensionally by bridging two C$$_{60}$$ molecules with the covalently bonded Co atom.

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Category:Materials Science, Multidisciplinary

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