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Report No.
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Characteristics and experimental evaluation of super-heat-resisting Nb-based and Mo-based Alloys

Morinaga, Masahiko*; not registered; not registered; not registered

[PURPOSE] Nb-based and Mo-basd alloys have been investigated in order to develop the frontiers of matelials technique which will be utililized in the environment of high-temperature liquid alkali metals. In this study, both mechanical properties and corrosion resistance to liquid Li were evaluated for two designed Mo-based alloys, Mo-15Re-0.1Zr and Mo-15Re-0.1Zr-0.1Ti. In addition, a series of corrosion test was performed with provisionally designed Nb-based alloys, Nb-(1-4)Hf. [EXPERIMENTAL METHODS] (1)High-temperature tensile test : A tensile test in the Ar atmosphere was carried out at 1473K for the designed Mo-based alloys. Commercial TZM alloy was also tested as a reference. (2)High-temperature creep test : A Creep test in the Ar atmosphere was performed at 1473K under the several applied stress levels for the designed Mo-based alloys. (3)Workability test : A three-point bend test was carried out at room temperature to evaluate the workability of the designed Mo-based alloys. (4)Corrosion resistance to liquid Li : Both the provisionally desingned Nb-based alloys and the designed Mo-based alloys were immersed in the liquid Li at 1473K. The weight change was measured as an indication of the corrosion resistance. Also, the Auger electron spectroscopy analysis was performed with several specimens to examine the surface state of them after corrosion tests. [RESULTS AND DISCUSSIONS] (1)High-temperature tensile properties : The designed Mo-based alloys were superior in the tensile properties at 1473K to the commercial TZM alloy. In fact, both the tensile and yield strengths of them were about 1.5 and 2.3 times higher than the TZM alloy, respectively. (2)High-temperature creep properties : The creep rate of the designed Mo-based alloys at 1473K was lower, compared to other solid solution hardening Mo-based alloys, but higher than the precipitation hardening TZM alloy. (3)Workability : The workability of the designed Mo-based alloys was satisfactory regardless ...

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