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ヨウ素の不活性ガス中拡散係数測定試験(III)

A Study of iodine diffusion in rare gases(III)

佐川 憲彦*

Sagawa, Norihiko*

希ガス中におけるヨウ化セシウム蒸気の拡散係数を、Stefan法を改良した方法を用いて測定した。拡散カラム底部でヨウ化セシウム結晶を溶融し、拡散カラム中の希ガスをヨウ化セシウム蒸気で飽和にし、拡散カラム頂部のバルブを開いて、拡散して来る蒸気を搬送ガスによってイオン化センサーに導いた。ヨウ化セシウム濃度をイオン化センサーで連続測定し、その出力電流の過渡応答を解析することにより、拡散係数を測定した。アルゴンガス、クリプトンガスおよびキセノンガス中において631$$sim$$691$$^{circ}C$$の温度範囲で求めたヨウ化セシウム蒸気の拡散係数には、温度上昇とともに増加する傾向が認められるが、それぞれのガス中の拡散係数には有意な差は認められなかった。

The diffusion coefficient of cesium iodide vapor in rare gases was determined by a modified Stefan's method. The rare gas in a diffusion column was saturated with vapor of the cesium iodide, crystals of which were heated to melt at the bottom of the column. By opening a valve united at a top of the column, the vapor diffusing through the column was transferred with the carrier rare gas to an ionization sensor. The concentration of cesium iodide in the carrier gas was continuously monitored with the sensor. The diffusion coefficient was determined by analyzing the transient response of the concentration. Increasing tendency with temperature is observed in the coefficients obtained in argon, kripton and xenon at temperatures between 631 and 691 $$^{circ}$$C and no significant difference among the coefficients in argon, krypton and xenon.

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