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Model of Oxygen Potential of (Pu$$_{0.3}$$U$$_{0.7}$$)O$$_{2pm X}$$ and (Np$$_{0.02}$$Am$$_{0.02}$$Pu$$_{0.3}$$U$$_{0.66}$$)O$$_{2-X}$$ based on Lattice Defect Theory

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加藤 正人   ; 青野 茂典; 木原 義之; 小無 健司*

Kato, Masato; Aono, Shigenori; Kihara, Yoshiyuki; Konashi, Kenji*

(Pu$$_{0.3}$$U$$_{0.7}$$)O$$_{2pm X}$$(Np$$_{0.02}$$Am$$_{0.02}$$Pu$$_{0.3}$$U$$_{0.66}$$)O$$_{2-X}$$の酸素ポテンシャルについて、格子欠陥理論を用いて整理し、モデル化した。得られた式は、O/Mと温度を関数として酸素ポテンシャルを良く表すことができ、文献のデータと良く一致した。

The model of oxygen potential of (Pu$$_{0.3}$$U$$_{0.7}$$)O$$_{2pm X}$$ was derived by experimental data set based on the lattice defect theory. In the model, the oxygen potential is calculated as a function of O/M and the temperature of fuel. The oxygen potential was evaluated by the crossed point of two lines of oxygen potential in the hypo-stoichiometric region and in the hyper-stoichiometric region. The oxygen potential of (Np$$_{0.02}$$Am$$_{0.02}$$Pu$$_{0.3}$$U$$_{0.66}$$)O$$_{2-X}$$was also evaluated and compared with that of (Pu$$_{0.3}$$U$$_{0.7}$$)O2-X

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