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Simultaneous observation of volatility of Zr, Hf, and Rf chlorides

Sato, Tetsuya   ; Tsukada, Kazuaki  ; Asai, Masato  ; Akiyama, Kazuhiko*; Haba, Hiromitsu*; Toyoshima, Atsushi; Ono, Sawako*; Hirai, Toshiyuki*; Goto, Shinichi*; Ichikawa, Shinichi; Nagame, Yuichiro ; Kudo, Hisaaki*

$$^{85}$$Zr, $$^{169}$$Hf, and $$^{261}$$Rf were produced simultaneously from $$^{rm nat}$$Ge($$^{18}$$, ${it x}$n), $$^{rm nat}$$Gd($$^{18}$$O, ${it x}$n), and $$^{248}$$Cm($$^{18}$$O, 5n) reactions, respectively, and the volatility of their chlorides was examined using an isothermal gas chromatographic system. The observed gas chromatogram indicated that ZrCl$$_4$$, HfCl$$_4$$, and RfCl$$_4$$ had almost similar volatility.

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