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Unravelling the role of steps in Cu$$_{2}$$O formation via hyperthermal O$$_{2}$$ adsorption at Cu(410)

Okada, Michio*; Vattuone, L.*; Gerbi, A.*; Savio, L.*; Rocca, M.*; Moritani, Kosuke*; Teraoka, Yuden; Kasai, Toshio*

We report a study on the oxidation process of Cu(410) using high-resolution electron energy loss spectroscopy and X-ray photoemission spectroscopy using synchrotron radiation. We demonstrate that a hyperthermal O$$_{2}$$ molecular beam (HOMB) is an efficient tool to fabricate Cu$$_{2}$$O thin film also at room temperature. The efficiency of the Cu$$_{2}$$O formation in the initial stages depends on the angle of incidence of HOMB. Step roughening, acting as a source of mobile precursor Cu adatoms and opening channels for bulk diffusion of the O atoms, is a key feature in determining the Cu$$_{2}$$O formation rate.

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Category:Chemistry, Physical

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