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Oxidation of Si(001) with a hyperthermal O-atom beam at room temperature; Suboxide distribution and residual order structure

Tagawa, Masahito*; Sogo, Chie*; Yokota, Kumiko*; Yoshigoe, Akitaka ; Teraoka, Yuden; Shimura, Takayoshi*

Synchrotron radiation photoelectron spectroscopy (SR-PES) and crystal truncation rod (CTR) scattering profiles were used to investigate an ultrathin SiO$$_{2}$$ overlayer on an Si(001) surface formed by a 5 eV O-atom beam at room temperature. The SR-PES spectra indicated that the suboxides in the O-atom-beam oxidized film were concentrated on the SiO$$_{2}$$ surface rather than at the Si/SiO$$_{2}$$ interface. The CTR scattering data of the O-atom-beam oxidation film had a lower intensity near (1 1 L) (0.3-L-0.8), suggesting a lower content of the SiO$$_{2}$$ ordered structure in the oxide film. An inverse diffusion of the interstitial Si atoms in the oxidation kinetics can explain the data.

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Category:Physics, Applied

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