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Thermal-swing extraction of Cadmium(II) by thermosensitive polymer gel crosslinked with Encapsulating hexadentate ligand

Takeshita, Kenji*; Ishida, Keigo; Nakano, Yoshio*; Matsumura, Tatsuro  

Thermal-swing extraction of Cd(II) with a thermosensitive gel, poly-N-isopropylacrylamide (NIPA) crosslinkedwith a podand, N,N,N',N'-tetrakis(4-propenyl-oxy-2-pyridylmethyl)ethylenediamine (TPPEN), was examined. Cd(II) was extracted selectively in the gel swollen at 5$$^{circ}$$C andreleased from the gel shrunken at 40$$^{circ}$$C. The difference in thedistribution ratios of Cd(II) between these temperatures wasmore than 30 times.

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Category:Chemistry, Multidisciplinary

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