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Report No.
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Synthesis of americium trichloride by the reaction of americium nitride with cadmium chloride

Hayashi, Hirokazu ; Takano, Masahide ; Akabori, Mitsuo; Minato, Kazuo 

Americium trichloride was synthesized by the reaction of americium nitride with cadmium chloride at 600-660 K in a dynamic vacuum. The product was hexagonal AmCl$$_3$$, of which lattice parameters were determined to be $$a_{0}$$ = 0.7390 and $$c_{0}$$ = 0.4215 nm. The results indicate that high purity AmCl$$_3$$ samples, in which the oxychloride was not found, were prepared without the use of corrosive reagents. The reaction of the nitrides with cadmium chloride is suitable for synthesis of high purity actinide and lanthanide chlorides.

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Category:Chemistry, Physical

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