Regioselectivity control of radiation-induced reaction; Electron beam-induced Fries rearrangement of sulfonamide within -cyclodextrin inclusion complex

Kato, Jun*; Kakehata, Hiroyuki*; Maekawa, Yasunari; Yamashita, Takashi*

EB (electron beam) irradiation of sulfonamide within -cyclodextrin (-CD) inclusion complex in the solid state induced the solvent-free Fries rearrangement, which proceeded at a shorter reaction time with reversed regioselectivity by inclusion into -CD, compared with that of sulfonamide crystals; the -CD as a restricted nanospace had much effect on the reactivity and regioselectivity of the solvent-free EB-Fries rearrangement.

Language	:	English
Journal	:	Chemical Communications
Volume	:
Number	:	43
Pages	:	p.4498 - 4500
Publication Year/Month	:	2006/11
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Paper URL	:	https://doi.org/10.1039/B606689E
DOI for research data	:
Keywords	:	no keyword
Research Facility	:	電子加速器
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Article of JAEA R&D Review	:
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InCites™	:	Percentile:40.28 Category:Chemistry, Multidisciplinary
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Registration No. : AA20060476
JAEA Abstracts No. : 34001284
Paper Submission No. : 1453

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