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Picosecond pulse radiolysis study of solvated electrons in ionic liquid

Asano, Akira*; Kondo, Takafumi*; Yang, J.*; Nagaishi, Ryuji ; Takahashi, Kenji*; Yoshida, Yoichi*

The spectrum and kinetic behavior of solvated electrons in DEMMA-TFSI and DEMMA-BF$$_{4}$$ ionic liquids (ILs) were investigated by using nanosecond pulse radiolysis technique. The reactions of the solvated electrons with pyrene and biphenylene were studied. The molar extinction coefficent and G value of the solvated electrons in ILs were estimated. The formation of the solvated electrons in IL on picosecond time scale was observed by picosecond pulse radiolysis.

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