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Neutron powder diffraction experiments on the layered triangular-lattice antiferromagnets RbFe(MoO$$_4$$)$$_2$$ and CsFe(SO$$_4$$)$$_2$$

Inami, Toshiya

Powder specimens of the layered triangular lattice antiferromagnets RbFe(MoO$$_4$$)$$_2$$ and CsFe(SO$$_4$$)$$_2$$ were prepared and neutron powder diffraction experiments were carried out in order to determine the magnetic structure. Magnetic structure of both compounds is so-called 120$$^circ$$ structure in the triangular plane and incommensurate between the plane. The ordered moments are confined in the basal $$ab$$-plane. It is also found that RbFe(MoO$$_4$$)$$_2$$ shows structural phase transition at around 190 K from $$Pbar{3}m1$$ to $$Pbar{3}$$.

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Category:Chemistry, Inorganic & Nuclear

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