Am(III)/Eu(III) separation with TPEN

Matsumura, Tatsuro  ; Takeshita, Kenji*

We are developing a new MA/Ln separation process with TPEN derivatives for P&T technology. TPEN is a hexadentate ligand and a kind of podand type molecule and can encapsulate a metal ion. TPEN has good selectivity of Am(III) from Ln(III). However, there is a serious problem for the practical application. This is to the dissolution of a slight amount of TPEN to water. In this study, the hydrophobicity of TPEN is improved by introducing alkyl groups and the effect of the introduction of alkyl groups on the separation of Am(III) and Eu(III) is examined. We synthesized three derivatives successfully. The derivatives were examined both the extractability and selectivity of Am(III) and Eu(III). One of them, tpdben, showed good selectivity and the maximum separation factor, SF, was 35 at pH 5.06. A hydrophobic derivative of TPEN that has potential of application to the MA/Ln separation process was synthesized successfully.