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Single crystalline $$beta$$-FeSi$$_{2}$$ grown using high-purity FeSi$$_{2}$$ source

Goto, Kohei*; Suzuki, Hirokazu*; Udono, Haruhiko*; Kikuma, Isao*; Esaka, Fumitaka  ; Uchikoshi, Masahito*; Isshiki, Minoru*

We have investigated the effect of FeSi$$_{2}$$ source purity on the electrical property of $$beta$$-FeSi$$_{2}$$ grown from solution. A high purity FeSi$$_{2}$$ source avoided a contamination of Cu and W metals was synthesized by melting a high purity Fe (5N) and Si (5N-up) in a quartz ampoule. The $$beta$$-FeSi$$_{2}$$ crystals grown using the high purity FeSi$$_{2}$$ and Zn solvent showed n-type conduction, whereas those grown using the arc-melted FeSi$$_{2}$$ showed p-type. From the SIMS analysis of the grown crystals, we found that dominant impurity concentrations in the p-type crystals were higher than those in the n-type ones.

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Category:Materials Science, Multidisciplinary

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