A Dinuclear Ni(-H)Ru complex derived from H $_{2}$

Ogo, Seiji*; Kabe, Ryota*; Uehara, Keiji*; Kure, Bunsho*; Nishimura, Takashi*; Menon, S. C.*; Harada, Ryosuke*; Fukuzumi, Shunichi*; Higuchi, Yoshiki*; Ohara, Takashi ; Tamada, Taro; Kuroki, Ryota

A novel dinuclear nickel-ruthenium complex with a bridging hydrido ligand, a Ni(-H)Ru complex, was obtained from the reaction of a dinuclear NiRu aqua complex with dihydrogen (H $_{2}$ ) in water under ambient conditions. The structure of the Ni(-H)Ru complex was unequivocally determined by neutron analysis. This is the first crystal structure of (six-coordinated Ni)(-H)M (M=transition metal atoms) that is similar to the core structure of the proposed active form of the [NiFe]hydrogenase.

Language	:	English
Journal	:	Science
Volume	:	316
Number	:	5824
Pages	:	p.585 - 587
Publication Year/Month	:	2007/04
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Paper URL	:	https://doi.org/10.1126/science.1138751
DOI for research data	:
Keywords	:	no keyword
Research Facility	:	JRR-3M(研究炉3)
Press Release	:	水素活性化酵素のモデル化に成功; 水素エネルギー研究開発へ応用
Article of JAEA R&D Review	:	Observation of a Key Hydrogen Atom in an Enzymatic Reaction; Neutron Structure Analysis of a Compound Modeling the Reaction Center of [NiFe]Hydrogenase[/]
Cooperating Institute	:	兵庫県立大学; 九州大学; 大阪大学

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Registration No. : AA20070060
JAEA Abstracts No. : 36000977
Paper Submission No. : 4289

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