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Report No.
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Planar doping of crystalline fullerene with cobalt

Lavrentiev, V.*; Naramoto, Hiroshi*; Narumi, Kazumasa; Sakai, Seiji; Avramov, P.

A study of 100 keV Co$$^{+}$$-implanted C$$_{60}$$ films with Rutherford Backscattering and Raman spectroscopy has revealed the pronounced cobalt translation from the surface layer of amorphous carbon into the deeper crystalline fullerene due to post-implantation annealing at 300 $$^{circ}$$C. Carbon density gradient along the film depth is discussed as a driving force of this effect. Cobalt deficit in the doped fullerene layer, detected by means of ion beam analysis, suggests ionization of the C$$_{60}$$ molecules under the collisions with 2 MeV He$$^{+}$$ ions.

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Category:Chemistry, Physical

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