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ESR spectra of N$$^{4+}$$ or P$$^{4+}$$ doped polyaniline

Ota, Nobuaki*; Nakagawa, Seiko*; Nishiyama, Fumitaka*; Morishita, Norio; Oshima, Takeshi

A bulk with 0.5-1 mm thickness of polyaniline was irradiated by the 3MV Tandem accelerator at the Takasaki Ion Accelerators for Advanced Radiation Application (TIARA) facility. ESR spectra of N$$^{4+}$$ or P$$^{4+}$$ doped polyaniline were measured at 77 K. A broad peak of polyaniline radical was observed. Except for polyaniline radical, new signals were also appeared when the fluence of doped N$$^{4+}$$ was less than 2$$times$$10$$^{12}$$ions/cm$$^{2}$$ and that of P$$^{4+}$$ was more than 6$$times$$10$$^{12}$$ions/cm$$^{2}$$.

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