The Study of formations and reactions of solvated electrons in ionic liquids by using pulse radiolysis

Asano, Akira*; Kondo, Takafumi*; Yang, J.*; Taguchi, Mitsumasa; Nagaishi, Ryuji ; Takahashi, Kenji*; Yoshida, Yoichi*

The spectrum and kinetic behavior of solvated electrons in DEMMA-TFSI and DEMMA-BF $_{4}$ ionic liquids (ILs) were investigated by using nanosecond pulse radiolysis technique. The reactions of the solvated electrons with pyrene were studied. The molar extinction coefficient and G value of the solvated electrons in ILs were estimated to be 2.210 $^{4}$ M $^{-1}$ cm $^{-1}$ (at 1100nm) and 0.9#100eV $^{-1}$ . The formation of the solvated electrons in IL on picosecond time scale was observed by picosecond pulse radiolysis.

Language	:	Japanese
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Meeting title	:	第50回放射線化学討論会
Held date	:	2007/10
Location (city)	:	宇治
Location (country)	:	日本
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Keywords	:	no keyword
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Registration No. : BB20072654
JAEA Abstracts No. :
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