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Ion-irradiation effects of hydrogen absorption in palladium metal

Yoneda, Yasuhiro   ; Tamura, Kazuhisa   ; Abe, Hiroshi; Oshima, Takeshi; Morimoto, Ryo*; Uchida, Hirohisa*; Mizuki, Junichiro

The effect of ion irradiation on palladium (Pd) metal was investigated by hydrogen-absorption measurements, SEM microscopy and synchrotron X-ray diffraction. N$$^+$$ irradiation was made with an acceleration energy 350 keV. The initial hydrogen absorption rate of the irradiated Pd was three times larger than that of non-irradiated Pd. The microscopic structure was investigated by using the pair-distribution function (PDF) obtained by X-ray diffraction. Although the average structure of the Pd was f.c.c, the Pd atoms displaced and two occupancy sites are revealed. This site occupancy is closely related with the hydrogen-absorption rate.

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