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Simultaneous recovery of all actinides from spent nuclear fuel by carbamoylmethylphosphine oxide in fluorinated diluents

Ozawa, Masaki; Iwai, Takehiko*; Babain, V.*; Shadrin, A.*

Bifunctional organophosphorus extractants dissolved in polar fluorinated diluents were studied aiming at directly recovering all f-elements from the dissolver solution of spent nuclear fuel. Distribution ratios of U, Np and Pu were sufficiently high for 0.4$$sim$$0.8MCMPO in this solvent system, and combination of salt-free, methylamine carbonate (MAC), etc, were evaluated to obtain fractional stripping of f-elements. Static multi-stage extraction using artificial FBR dissolver solution supported the process feasibility.

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