Intense laser-induced decomposition of mass-selected 2-, 3-, and 4-methylaniline cations

Itakura, Ryuji; Tanaka, Takatsugu*; Kuwata, Mikinori*; Suzuki, Hideaki*; Yamanouchi, Kaoru*

Photodecomposition processes of 2-, 3-, and 4-methylaniline cations induced by a moderately intense ( 10 $^{11}$ W/cm $^{2}$ ) visible nanosecond laser field and an intense ( 10 $^{15}$ W/cm $^{2}$ ) UV femtosecond laser field are investigated using a tandem mass spectrometer. Highly unsaturated fragment cations such as C $_{6}$ H $_{2}$ $^{+}$ , C $_{6}$ H $_{3}$ $^{+}$ are dominantly produced by the nanosecond laser, while less unsaturated smaller fragment cations such as C $_{3}$ H $_{3}$ $^{+}$ , C $_{4}$ H $_{4}$ $^{+}$ , C $_{5}$ H $_{5}$ $^{+}$ are produced mainly by the femtosecond laser.

Language	:	English
Journal	:	Chemical Physics Letters
Volume	:	462
Number	:	1-3
Pages	:	p.27 - 30
Publication Year/Month	:	2008/09
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Paper URL	:	https://doi.org/10.1016/j.cplett.2008.06.092
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Keywords	:	no keyword
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Registration No. : AA20080166
JAEA Abstracts No. : 36001264
Paper Submission No. : 4558

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