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Adsorption capacity of tritium on mordenite at low temperature

Kawamura, Yoshinori; Iwai, Yasunori; Hayashi, Takumi; Yamanishi, Toshihiko; Munakata, Kenzo*

Synthesis zeolite is the candidate material of the separation column of the gas chromatograph for the hydrogen isotope analysis. Mordenite (MOR) is one of the zeolite, and has been reported that the MOR column can separate hydrogen isotope at about 200 K. So, the present authors have investigated the adsorption capacities of H$$_{2}$$ and D$$_{2}$$ on MOR at various temperatures, and have predicted the adsorption isotherms of HD, HT, DT and T$$_{2}$$. In this work, the adsorption capacities of tritium on MOR at 77 K and 87 K were investigated, and they were compared with the predicted isotherms. The observed isotherm at 87 K agreed with the predicted isotherm fairly well. However, at 77 K, the adsorption capacity at low presser region was smaller than the isotherm of D$$_{2}$$.

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Category:Nuclear Science & Technology

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