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Formation of multi-layer structures in Bi$$_{3}$$Pb$$_{7}$$ intermetallic compounds under an ultra-high gravitational field

Mashimo, Tsutomu; Iguchi, Yusuke*; Bagum, R.*; Sano, Tomokazu*; Sakata, Osami*; Ono, Masao  ; Okayasu, Satoru  

Ultra-high gravitational field (Mega-gravity field) can realize the sedimentation of atoms (diffusion) even in solids, and is expected to form a composition-graded structure and/or nonequilibrium phase in multi-component condensed matter. We had realized the sedimentation of substitutional solute atoms in miscible systems (Bi-Sb, In-Pb, etc.). In this study, the mega-gravity experiment at high temperature was performed on a thin-plate sample (0.7 mm in thickness) of intermetallic compound Bi$$_{3}$$Pb$$_{7}$$. A visible four-layers structure appeared, which indicated different microscopic structures. In the lowest-gravity region layer, Bi phase appeared. In the mid layers, the composition-graded structure was formed, while the powder X-ray diffraction patterns show difference. Such multi-layers structure was expected to show unique physical properties such as superconductivity. Keywords: Sedimentation of atoms, Ultra-high gravity field, Bi$$_{3}$$Pb$$_{7}$$, Graded structure.

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