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Anion-exchange behavior of element-105 (Db) in HF/HNO$$_3$$ solutions using a newly developed on-line experimental system

Tsukada, Kazuaki  ; Kasamatsu, Yoshitaka; Asai, Masato  ; Toyoshima, Atsushi; Ishii, Yasuo; Li, Z.; Kikuchi, Takahiro; Sato, Tetsuya   ; Nishinaka, Ichiro; Nagame, Yuichiro ; Goto, Shinichi*; Hasegawa, Taichi*; Kudo, Hisaaki*; Fujisawa, Hiroyuki*; Oe, Kazuhiro*; Yahagi, Wataru*; Sato, Wataru*; Shinohara, Atsushi*; Nanri, Tomohiro*; Araki, Mikio*; Yokoyama, Akihiko*; Fan, F.*; Kudo, Yuki*; Oura, Yasuji*

Anion-exchange chromatographic behavior of element 105, dubnium (Db), produced in the $$^{248}$$Cm($$^{19}$$F,5n)$$^{262}$$Db reaction is investigated together with the homologues Nb and Ta in HF/HNO$$_3$$ mixed media using a newly developed on-line experimental system. The result indicates that the adsorption sequence on the anion-exchange resin is Ta$$gg$$Nb$$geq$$Db, and the fluoride complex formation of Db is expected to be weaker than that of homologues.

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