Redox equilibria of the U $^{4+}$ /U $^{3+}$ and U $^{3+}$ /U couples in molten LiCl-RbCl eutectic

Nagai, Takayuki ; Uehara, Akihiro*; Fujii, Toshiyuki*; Shirai, Osamu*; Sato, Nobuaki*; Yamana, Hajimu*

Formal redox potentials of the U $^{4+}$ /U $^{3+}$ and U $^{3+}$ /U couples in molten LiCl-RbCl eutectic were determined by cyclic voltammetry. These redox potentials were more negative than those in the LiCl-KCl eutectic but positive comparing to those in the NaCl-CsCl eutectic. This relation would be correlated with the averaged alkali cation radius.

Language	:	English
Journal	:	Denki Kagaku Oyobi Kogyo Butsuri Kagaku
Volume	:	77
Number	:	8
Pages	:	p.614 - 616
Publication Year/Month	:	2009/08
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Paper URL	:	https://doi.org/10.5796/electrochemistry.77.614
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Keywords	:	no keyword
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Article of JAEA R&D Review	:
Cooperating Institute	:	京都大学原子炉実験所

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Registration No. : AA20080747
JAEA Abstracts No. : 37001533
Paper Submission No. : 6537

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Redox equilibria of the U/U and U/U couples in molten LiCl-RbCl eutectic

Redox equilibria of the U $^{4+}$ /U $^{3+}$ and U $^{3+}$ /U couples in molten LiCl-RbCl eutectic