Local lattice distortion in the giant negative thermal expansion material MnCuGeN

Iikubo, Satoshi*; Kodama, Katsuaki   ; Takenaka, Koshi*; Takagi, Hidenori*; Takigawa, Masashi*; Shamoto, Shinichi  

Giant negative thermal expansion is achieved in antiperovskite manganese nitrides when the sharp volume change associated with magnetic ordering is broadened by substitution. In this Letter, we address the unique role of the "magic" element, Ge, for such broadening in MnCuGeN. We present evidence for a local lattice distortion well described by the low-temperature tetragonal () structure of MnGeN for a range of , where the overall structure remains cubic. This structural instability shows a strong correlation with the broadness of the growth of the ordered magnetic moment and, hence, is considered to trigger the broadening of the volume change.