have an anomalous endohedral structure? Synthesis and single crystal X-ray structure of the carbene adductAkasaka, Takeshi*; Kono, Takayoshi*; Takematsu, Yuji*; Nikawa, Hidefumi*; Nakahodo, Tsukasa*; Wakahara, Takatsugu*; Ishitsuka, Midori*; Tsuchiya, Takahiro*; Maeda, Yutaka*; Liu, M. T. H.*; Yoza, Kenji*; Kato, Tatsuhisa*; Yamamoto, Kazunori; Mizorogi, Naomi*; Slanina, Z.*; Nagase, Shigeru*
We report here the results on single crystal X-ray crystallographic analysis of the Gd@C carbene adduct (Gd@C(ad), Ad=adamantylidene). The Gd atom in Gd@C(Ad) is located at an off-centered position near a hexagonal ring in the C2v-C cage, as found for M@C (M = Sc and La) and La@C(Ad). Theoretical calculation also confirms the position of the Gd atom in the X-ray crystal structure.
Language |
: | English |
|---|---|---|
Journal |
: | |
Volume |
: | 130 |
Number |
: | 39 |
Pages |
: | p.12840 - 12841 |
Publication Year/Month |
: | 2008/10 |
Paper URL |
: |
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Keywords |
: | no keyword |
Accesses |
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Percentile:84.42 Category:Chemistry, Multidisciplinary |
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