Frustrating the lamellar ordering transition of polystyrene--polyisoprene with a C $_{60}$ additive

Zhao, Y.; Hashimoto, Takeji; Douglas, J.*

We have made nanocomposites of a symmetric PS--PI BCP and C $_{60}$ , and have studied the impact of this nanoparticle on the morphology and thermodynamic nature of the lamellar BCP ordering transition. Increasing the C $_{60}$ concentration to a modest value as large as 1% by weight proves to be sufficient to frustrate BCP ordering altogether. Evidently, the addition of nanoparticles to BCP materials can lead to significant changes in the thermodynamics of BCP ordering and offers new opportunities for materials development based on these nanocomposites.

Language	:	English
Journal	:	Journal of Chemical Physics
Volume	:	130
Number	:	12
Pages	:	p.124901_1 - 124901_6
Publication Year/Month	:	2009/03
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Paper URL	:	https://doi.org/10.1063/1.3089667
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Keywords	:	no keyword
Research Facility	:	JRR-3実験利用棟(第2棟)
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Registration No. : AA20090695
JAEA Abstracts No. : 38000185
Paper Submission No. : 6776

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Frustrating the lamellar ordering transition of polystyrene--polyisoprene with a C additive

Frustrating the lamellar ordering transition of polystyrene--polyisoprene with a C $_{60}$ additive