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Study on the behavior of oxygen atoms in swift heavy ion irradiated CeO$$_{2}$$ by means of synchrotron radiation X-ray photoelectron spectroscopy

Iwase, Akihiro*; Ono, Hirotaka*; Ishikawa, Norito   ; Baba, Yuji  ; Hirao, Norie; Sonoda, Takeshi*; Kinoshita, Motoyasu*

To study the effects of swift heavy ion irradiation on cerium dioxide (CeO$$_{2}$$), CeO$$_{2}$$ sintered pellets were irradiated with 200 MeV Xe ions at room temperature. For irradiated and unirradiated samples, the spectra of X-ray photoelectron spectroscopy (XPS) were measured. XPS spectra for the irradiated samples show that the valence state of Ce atoms partly changes from +4 to +3. The amount of Ce$$^{3+}$$ state was quantitatively obtained as a function of ion-fluence. The relative amount of oxygen atom displacements, which are accompanied by the decrease in Ce valence state, is 3-5%. This value is too large to be explained in terms of elastic interactions between CeO$$_{2}$$ and 200 MeV ions. The experimental result suggests the contribution of 200 MeV Xe induced electronic excitation to the displacements of oxygen atoms.

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