Polyamorphism in tin tetraiodide

Fuchizaki, Kazuhiro*; Hase, Takaki*; Yamada, Akihiro*; Hamaya, Nozomu*; Katayama, Yoshinori; Funakoshi, Kenichi*

In situ synchrotron X-ray diffraction measurements on tin tetraiodide, which consists of SnI tetrahedral molecules at ambient pressure, have been performed. It was established that the liquid forms existing above and below 1.5 GPa, where the slope of the melting curve of the solid phase changes abruptly, have different structures. This discovery offers evidence of thermodynamically stable polyamorphism in general compounds as well as in elements. A possible phase diagram that includes the two amorphous states already found is proposed based on the pseudobinary regular solution model. The vertex-to-face orientation between the nearest molecules plays a key role in the transition from the low-pressure to the high-pressure liquid phase.