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Equation of state of hexagonal boron nitride

六方晶窒化ホウ素の状態方程式

渕崎 員弘*; 中道 猛史*; 齋藤 寛之; 片山 芳則

Fuchizaki, Kazuhiro*; Nakamichi, Takeshi*; Saito, Hiroyuki; Katayama, Yoshinori

六方晶窒化ホウ素の回折データを放射光X線を用いて、8GPaまでの圧力,1000Kまでの温度の範囲で測定し、その結果をBirch-Murnaghan及びParsafar-Mason状態方程式によって解析した。これらの状態方程式から得られた常温常圧での等温体積弾性率はほぼ一致した。しかしながら、約20GPaというその値は、以前に報告された値より明らかに小さい。今回の結果を正当化するX線回折パターンを示すとともに、大きな不一致の原因を議論する。

Diffraction data from hexagonal boron nitride were measured through in situ synchrotron X-ray measurements under pressures and temperatures up to about 8GPa and 1000K, respectively. They were analyzed in the light of Birch Murnaghan's and Parsafar Mason's equations of state. The isothermal bulk moduli at ambient conditions obtained from these equations almost coincide. However, the value, about 20GPa, is appreciably smaller than the one reported previously. The X-ray diffraction patterns by which the current result is justified are presented. The possible origin of a large discrepancy in the values is discussed.

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パーセンタイル:68.93

分野:Physics, Condensed Matter

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