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Oxidation of element 102, nobelium, with flow electrolytic column chromatography on an atom-at-a-time scale

Toyoshima, Atsushi; Kasamatsu, Yoshitaka*; Tsukada, Kazuaki; Asai, Masato; Kitatsuji, Yoshihiro; Ishii, Yasuo; Tome, Hayato; Nishinaka, Ichiro; Haba, Hiromitsu*; Oe, Kazuhiro*; Sato, Wataru*; Shinohara, Atsushi*; Akiyama, Kazuhiko*; Nagame, Yuichiro

We report here on the successful oxidation of element 102, nobelium (No), on an atom-at-a-time scale in 0.1 M $$alpha$$-hydroxyisobutyric acid ($$alpha$$-HIB) solution using newly developed flow electrolytic column chromatography. It is found that the most stable No$$^{2+}$$ is oxidized to No$$^{3+}$$ within 3 min and that the oxidized No complex with $$alpha$$-HIB holds the trivalent state in the column above the applied potential of 1.0 V.

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Category:Chemistry, Multidisciplinary

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