Fluorescence properties of a uranyl(V)-carbonate species [U(V)O $_{2}$ (CO $_{3}$ ) $_{3}$ ] $^{5-}$ at low temperature

Grossmann, K.*; Arnold, T.*; Ikeda, Atsushi ; Steudner, R.*; Geipel, G.*; Bernhard, G.*

Fluorescence properties of a uranyl(V) tricarbonate complex were determined at T = 153 K by time-resolved laser-induced fluorescence spectroscopy (TRLFS) for the first time. The fluorescence emission bands of the uranyl(V) tricarbonate complex were detected between 380 and 440 nm with the maxima at 404.7 nm (excitation with 255 nm) and 413.3 nm (excitation with 408 nm). Besides, the fluorescence lifetime was determined to be 120 micro-sec at 153 K.

Language	:	English
Journal	:	Spectrochimica Acta, Part A
Volume	:	72
Number	:	3
Pages	:	p.449 - 453
Publication Year/Month	:	2009/03
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Keywords	:	no keyword
Research Facility	:	SPring-8(大型放射光施設)
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Cooperating Institute	:	Forschungszentrum Dresden-Rossendorf

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Registration No. : AA20090202
JAEA Abstracts No. : 37001052
Paper Submission No. : 6047

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Fluorescence properties of a uranyl(V)-carbonate species [U(V)O(CO)] at low temperature

Fluorescence properties of a uranyl(V)-carbonate species [U(V)O $_{2}$ (CO $_{3}$ ) $_{3}$ ] $^{5-}$ at low temperature