Refine your search:     
Report No.

Local and electronic structure of Am$$_{2}$$O$$_{3}$$ and AmO$$_{2}$$ with XAFS spectroscopy

Nishi, Tsuyoshi; Nakada, Masami  ; Suzuki, Chikashi ; Shibata, Hiroki ; Ito, Akinori; Akabori, Mitsuo; Hirata, Masaru 

XAFS studies were performed in a study of americium sesquioxide (Am$$_{2}$$O$$_{3}$$) with A-type rare earth oxide structure and americium dioxide (AmO$$_{2}$$) with fluorite structure. EXAFS results for Am-L$$_{3}$$ absorption edge of Am$$_{2}$$O$$_{3}$$ and AmO$$_{2}$$ were good agreement with the crystallographic data from X-ray diffraction analysis. In order to characterize XANES in aspect of the electronic states, the theoretical assignments for the Am$$_{2}$$O$$_{3}$$ and AmO$$_{2}$$ were performed with the all-electron full potential linearized augmented plane wave (FP-LAPW) method. The theoretical XANES spectra of Am$$_{2}$$O$$_{3}$$ and AmO$$_{2}$$ well reproduced the experimental ones. In addition, it was found that the white line peak was created due to the interaction between Am-d and O-p components, and the broad peak and the tail peak were created due to the interaction between Am-d and O-d component.



- Accesses




Category:Materials Science, Multidisciplinary



[CLARIVATE ANALYTICS], [WEB OF SCIENCE], [HIGHLY CITED PAPER & CUP LOGO] and [HOT PAPER & FIRE LOGO] are trademarks of Clarivate Analytics, and/or its affiliated company or companies, and used herein by permission and/or license.