Mn
O
(NO) oxynitrate comprising 
=3/2 honeycomb latticeSmirnova, O.*; Azuma, Masaki*; Kumada, Nobuhiro*; Kusano, Yoshihiro*; Matsuda, Masaaki; Shimakawa, Yuichi*; Takei, Takahiro*; Yonesaki, Yoshinori*; Kinomura, Nobukazu*
Neutron diffraction and FT-IR analysis revealed that the novel oxynitrate BiMnO (NO) prepared by hydrothermal synthesis is of a new structural type including flat NO layers alternating with blocks of two PbSb
O
-like layers. Mn
(=3/2) forms a regular honeycomb lattice, and magnetic susceptibility data indicated two-dimensional magnetism. Despite its Weiss constant of 
257K, no long-range ordering was observed down to 0.4K because of the magnetic frustration due to the competition between the nearest and the next-nearest antiferromagnetic interactions.
Language |
: | English |
|---|---|---|
Journal |
: | |
Volume |
: | 131 |
Number |
: | 23 |
Pages |
: | p.8313 - 8317 |
Publication Year/Month |
: | 2009/05 |
Paper URL |
: |
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Keywords |
: | no keyword |
Research Facility |
: |
Accesses |
: |
- Accesses |
|---|---|---|
InCites™ |
: |
Percentile:91.9 Category:Chemistry, Multidisciplinary |
Altmetrics |
: |
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