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Well-ordered arrangement of Ag nanoparticles in SiO$$_{2}$$/Si by ion implantation

Ninakuchi, Yuki*; Saito, Masahiro*; Isshiki, Toshiyuki*; Nishio, Koji*; Nishiyama, Fumitaka*; Yamamoto, Shunya; Sasase, Masato*; Takahiro, Katsumi*

In the course of Ag implantation into thermally grown SiO$$_{2}$$ films, we found well-ordered Ag nanoparticles in the vicinity of SiO$$_{2}$$/Si interface. SiO$$_{2}$$ films of 300 nm thick were grown on single crystalline Si(111) substrates. The SiO$$_{2}$$/Si samples were implanted with 350 keV-Ag ions to a fluence of 1$$times$$10$$^{17}$$ ions/cm$$^{2}$$. The Ag-implanted SiO$$_{2}$$/Si samples were characterized by Rutherford backscattering spectrometry (RBS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and cross sectional transmission electron microscopy (XTEM). The Ag concentration depth profiles obtained by RBS and XPS were non-Gaussian, indicating that Ag atoms diffused significantly. XTEM revealed that well-arranged Ag nanoparticles of 30 nm and 2 nm in diameter were distributed near the projected range and the SiO$$_{2}$$/Si interface, respectively.

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