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Dynamic nuclear polarization using free radicals produced by radiolysis and photolysis

Kumada, Takayuki   ; Noda, Yohei; Koizumi, Satoshi; Hashimoto, Takeji

We succeeded in dynamically polarizing UV-irradiated solid butanol. Unlike persistent radicals such as TEMPO, the butyl radicals produced by the UV-photolysis immediately decay by melting. We propose that free radicals produced by UV-photolysis are applicable to DNP-enhanced hyperpolarized liquid-state NMR.

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