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Percolation in radioactive-waste glass melt with RuO$$_2$$

Ogawa, Toru

Molten glass containing RuO$$_2$$ particles develops electronic conduction, which causes unstable operation of the joule-heated melter for the radioactive waste vitrification. Percolation behavior of molten glass-ruthenium oxide composites was examined by noting hierarchical formation process with four length scales. A low percolation threshold less than 1 vol% was reasonably reproduced by assuming the packing of soft RuO$$_2$$ rods in the primary aggregate, and applying Bruggeman's effective medium approximation for the higher aggregates and their clusters.

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Category:Materials Science, Ceramics

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