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Photoluminescence properties of mononuclear Eu(III) complex with tetradentate Schiff-base ligand

Ebato, Shota*; Tsuchimoto, Masanobu*; Watanabe, Masayuki   ; Nakajima, Kiyohiko*

Eu complexes of tetradentate Schiff-base ligand(L) have a octa-coordinated structure which ligand perpendicularly coordinated to the Eu center. It has been found that the counter cation, triethylammonium, formed hydrogen bonding with the complex with L. In this presentation, we investigated the Eu complex with L with tetraethylammonium as a counter cation which could not form hydrogen bonding with the complex.

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